"CV 1:2 Mux" is multiplying CV1 and CV2 together and sending it to both Oscillators. This is why you are hearing both oscillators respond to patching something into CV2. This is most normally used when you want a Pitch (CV1) and FM (CV2) going to both oscillators, typically an external FM source. Of course, what you are doing is also totally fine, as it creates an interesting loop of self-(re)modulation. "CV 1:2 Sum" is just another variant of this.
If you want the Oscillators to operate independently, eg. just want to FM Osc 2 using Osc 1, "CV1 : CV2" is a simpler mode, where CV 1 will only control Osc 1, and CV 2 only controls Osc 2. In this mode, if you patch Osc 1 into CV2, you'll then just hear Osc 2 being FM'd by Osc 1.
I know this isn't always totally clear, but as you pointed out, we did try to put all kinds of powerful features in there for you to discover wild new sounds!
Hope that helps.
- Rob